Guide Isospecific Polymerization of Olefins: With Heterogeneous Ziegler-Natta Catalysts

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The initial works of Ziegler and Natta were followed by an "explosion" of scientific papers and patents covering all aspects of polymerization chemistry, catalyst synthesis, and polymerization kinetics as well as the structural, chemical, physical, and technological characteristics of stereo regular polyolefins, polydienes, and olefin copolymers. It is sufficient to say that in the twenty-five years after the first publications more than 15, papers and patents appeared on subjects related to the area. The development brought about the establishment of several prominent groups of scientists occupied with the study of olefin polymerization.

In addition, many major chemical and petrochemical corporations throughout the world established labora- tories devoted to the development of the technology of catalyst synthesis and olefin polymerization. Read more Read less. Amazon Global Store US International products have separate terms, are sold from abroad and may differ from local products, including fit, age ratings, and language of product, labeling or instructions. Manufacturer warranty may not apply Learn more about Amazon Global Store.

Chinese Journal of Polymer Science , 35 12 , Budzelaar, Antonio Vittoria, Roberta Cipullo. Of Poisons and Antidotes in Polypropylene Catalysis.

Ziegler-Natta and Metallocene Catalysis Polymerization

Angewandte Chemie International Edition , 55 30 , Angewandte Chemie , 30 , New penta-ether as the internal donor in the MgCl2-supported Ziegler-Natta catalysts for propylene polymerization. Chinese Journal of Polymer Science , 34 3 , Polypropylene: Magnesium-Based Supported Catalysis. Yusuke Mitsushige, Brad P. Carrow, Shingo Ito, Kyoko Nozaki. Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide—palladium catalysts. Chemical Science , 7 1 , Microstructure of polypropylene and active center in Ziegler—Natta catalyst: effect of novel salicylate internal donor.

RSC Advances , 6 79 , Ziegler-Natta catalysts with novel internal electron donors for propylene polymerization. The influence of combined external donor and combined cocatalyst on propylene polymerization with a MgCl 2 -supported Ziegler-Natta catalyst in the presence of hydrogen. European Journal of Inorganic Chemistry , 29 , MgCl 2 -supported Ziegler-Natta catalyst containing dibenzoyl sulfide donor for propylene polymerization. Polypropylene random copolymer in pipe application: Performance improvement with controlled molecular weight distribution.

Thermochimica Acta , , Heterophasic copolymers of polypropylene: Development, design principles, and future challenges. Journal of Applied Polymer Science , 5 , Heterogeneous Ziegler-Natta, metallocene, and post-metallocene catalysis: Successes and challenges in industrial application.

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MRS Bulletin , 38 03 , Journal of Macromolecular Science, Part B , 51 9 , Propylene polymerization over MgCl2-supported TiCl4 catalysts bearing different amounts of a diether internal electron donor: Extrapolation to the role of internal electron donor on active site. Journal of Applied Polymer Science , 2 , Polymer-Plastics Technology and Engineering , 50 4 , European Polymer Journal , 47 2 , Harshad R. Patil, Dhananjay G. Naik, Virendrakumar Gupta. Journal of Macromolecular Science, Part A , 48 3 , Poly propylene-co-ethylene produced with a conventional and a self-supported ziegler-natta catalyst: Effect of ethylene and hydrogen concentration on activity and polymer structure.

Yury V. Kissin, Robert I.

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Ethylene polymerization reactions with multicenter Ziegler-Natta catalysts-Manipulation of active center distribution. Luche Reduction. Kogure, Polymer , in print. Kogure, and T.

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Busico, P. Corradini, L. De Martino, F. Graziano, and A. Iadicicco, Makromol. Paukkeri, E.

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Salminen, Polymer , 35 , Cheng, Makromol. Cheng, J. Luciani, Makromol. Kuutti, Makromol. Busico, R. De Biasio, R. Cipullo, and P.